New models of interstellar gas–grain chemistry – I. Surface diffusion rates     

Deborah P. Ruffle  Eric Herbst 《Monthly notices of the Royal Astronomical Society》2000,319(3):837-850

In recent years it has become evident that large differences can exist between model results of grain-surface chemistry obtained from a rate equation approach and from a Monte Carlo technique. This dichotomy has led to the development of a modified rate equation method, in which a key element is the artificial slowing down of the diffusion rate of surface hydrogen atoms. Recent laboratory research into the surface diffusion rate of atomic hydrogen suggests that atomic hydrogen moves more slowly on grains than heretofore assumed. This research appears to lessen the need for modifications to the rate equation method. Based on the new laboratory work, we have developed appropriate models of gas-phase and grain-surface chemistry in quiescent dense cloud cores to examine the chemical effects of slowing down the rate at which atomic H can scan over dust surfaces. Furthermore, we have investigated the effect of slowing down the rate at which all species can move over grain surfaces.  相似文献   

Effects of stem density upon sediment retention by salt marsh cord grass,Spartina alterniflora loisel   总被引：1，自引：0，他引：1  

Mark L. Gleason  Deborah A. Elmer  Natalie C. Pien  John S. Fisher 《Estuaries and Coasts》1979,2(4):271-273

A laboratory experiment was conducted to determine whether retention of waterborne sand by salt marsh cordgrass, Spartina alterniflora Loisel, is directly related to the number of stems per unit area. Waves generated in a trough washed over a sloping beach planted with S. alterniflora sprigs: a range of stem densities (0–108 stems/m²) was examined in separate trials. The amount of sand accumulated after 60 waves is a positive nonlinear function of stem density. The greatest accretion coincided with the highest stem density tested. Shape of the beach profile was also strongly influenced by the number of stems per m².  相似文献   

The impact of vertebrate herbivores on wetland vegetation in Atchafalaya Bay, Louisiana     

D. Elaine Evers  Charles E. Sasser  James G. Gosselink  Deborah A. Fuller  Jenneke M. Visser 《Estuaries and Coasts》1998,21(1):1-13

Delta islands in the Atchafalaya and Wax Lake deltas in Atchafalaya Bay, Louisiana, are in an extremely dynamic successional phase. These islands initially supported large marshes dominated by the pioneering plant species Sagittaria latifolia and Sagittaria platyphylla. A general decrease in vegetated areas has occurred in the delta island marshes in the Atchafalaya Delta since about 1980, while in the Wax Lake Delta portion of the complex the vegetation still flourished. The Atchafalaya Delta provides an interesting setting for the study of herbivory because of the complex interaction of biotic and physical factors operating in this delta. We hypothesized that grazing by herbivores has a marked effect on vegetation in these developing marshes. To test this hypothesis, exclosures were erected on islands in both deltas in September 1985 and January 1986. Each set of exclosure treatments included an openly-grazed control area, an ungrazed area, an area allowing nutria grazing, and one allowing waterfowl grazing in each site. Results of the experiment, based on field sampling of vegetation, indicated decreases in plant biomass and changes in plant species composition in grazed treatments. Waterfowl and nutria reduced biomass aboul equally, but there was a more marked effect in the openly grazed areas. These findings may be extrapolated to sediment diversion areas along the Mississippi River.  相似文献   

Nonrenewable resources in economic, social, and environmental sustainability     

Deborah J. Shields 《Natural Resources Research》1998,7(4):251-261

This paper reviews the linkages among energy and mineral resources and economic, social, and environmental sustainability. Nonrenewable resources are shown to be integral components of sustainability, regardless of which paradigmatic definition of the concept is invoked. Potential measures of the degree to which nonrenewable resources contribute to or detract from sustainability are presented. We conclude that a set of such measures should be incorporated in the comprehensive framework of sustainability currently being developed by the Federal government. National scale indicators could be presented within the structure of the seven criteria from the Santiago Declaration, whereas a life cycle or materials flow approach could be used when sustainability of specific resources is at issue.  相似文献   

The effects of dock shading on the seagrass Halodule wrightii in Perdido Bay, Alabama     

Deborah J. Shafer 《Estuaries and Coasts》1999,22(4):936-943

Aboveground and belowground biomass, density, blade length, and chlorophyll content of seagrass growing directly under docks were compared with adjacent unshaded sites. The amount of light reduction due to dock shading was measured using quantum spherical irradiance meters. Seagrasses were present under docks; they were shaded such that light levels were 19% and 16% of surface irradiance, at shallow and deep sites, respectively. Shoot density was 40–47% lower in shaded plots than in unshaded plots; total biomass was 30–33% lower in shaded plots than in unshaded plots. In contrast, blade length and chlorophyll content were increased at shaded plots relative to unshaded plots. Seagrasses were not found under docks at light levels less than 14% of surface irradiance. These results are in agreement with published in situ compensation irradiance estimates of 15–18% for Halodule wrightii in Texas coastal waters. Shading effects were most apparent between the hours of 1000 and 1500; therefore, the light received during the early morning and late afternoon hours may be critical for plants growing under docks. The north-south orientation of the docks in this study is likely an important factor contributing to the continued survival and growth of the seagrasses.  相似文献   

An Interpretation of ISO Guidelines for the Certification of Geological Reference Materials   总被引：3，自引：0，他引：3  

Jean S. Kane  Philip J. Potts 《Geostandards and Geoanalytical Research》1999,23(2):209-221

Recommendations for the certification of reference materials, as published by the International Organisation for Standardisation (ISO), are reviewed and proposals made as to how they can be adapted for the certification of new geological reference materials. Whilst acknowledging the important contribution made by the large number of existing matrix-matched geological reference materials, it is recommended that future characterisation programmes should follow the ISO guidelines for certification, not the least so that laboratories can readily use the resultant samples to establish the traceability of geoanalytical results.  相似文献   

Shape analysis of Pacific seamounts   总被引：2，自引：0，他引：2  

Deborah K. Smith 《Earth and Planetary Science Letters》1988,90(4):457-466

Shape statistics have been compiled from 85 profiles of well-surveyed Pacific seamounts in the height range 140–3800 m. A flat-topped cone was fit to each seamount's cross-sectional profile maintaining the slopes of the sides as closely as possible. On each profile a basal widthd_b, a summit widthd_t, and a maximum heighth, were measured. The height-to-basal-radius ratio isξ_h is estimated by the ratio2hd_b and flatnessf by the ratiod_td_b. Slope angleφ = arctan(ε) is estimated fromε =2h(d_b − d_t). Summit height and basal radius are found to be highly correlated (r = 0.93). The 85-point sample mean of the height-to-basal-radius ratio isξ_h = 0.21 ± 0.08 implying that a seamount's summit height is typically one fifth its basal radius. Despite the high correlation, individual points show some scatter, and there may be groupings into different morphological types. For example, all but one of the seamounts with summit heights above 1000 m have values ofξ_h that are larger than the sample mean. The 85-point sample mean of flatness isf = 0.31 ± 0.18. Data points show a large scatter with values off varying between 0 (a pointy cone) and 0.69 (a flat-topped cone). A histogram representation of flatness, however, indicates that certain values off may be more common than others: the histogram shows a bimodal distribution with maxima occurring at values off in the ranges 0.10–0.20 and 0.35–0.50. Moreover, there is some evidence that the mean flatness decreases with summit height so that the preferred shape of a large-sized seamount may be a pointy cone. Slope angle has an 85-point sample mean ofφ = 18 ± 6°; individual values ofφ vary between 5° and 36°. In addition to having a lower than average mean flatness seamounts with heights above 2600 m also have a lower than average mean slope angle (15°). To determine which variables account for most of the observed variation in the seamount shapes, a multivariate principal component analysis was performed on the data using five shape variables (summit height, basal radius, summit radius, flatness, and slope). The analysis indicates that most of the variation is described by two variables: flatness and summit height.  相似文献   

Sensitivity of crop yields and land resource potential to climatic change in Ontario,Canada     

Barry Smit  Michael Brklacich  Robert B. Stewart  Ray McBride  Murray Brown  Deborah Bond 《Climatic change》1989,14(2):153-174

Increasing concentrations of atmospheric CO₂ and other greenhouse gases are expected to contribute to a global warming. This paper examines the potential implications of a climatic change corresponding to a doubling of atmospheric concentrations of CO₂ on crop production opportunities throughout Ontario, a major food producing region in Canada. The climate is projected to become warmer and drier, but the extent of these shifts are expected to vary from region to region within Ontario. The effect of this altered climate on crop yields and the area of land capable of supporting specific crops varies according to region, soil quality and crop type. Most notable are the enhanced opportunities for grains and oilseeds in the northern regions, and the diminished production prospects for most crops in the most southerly parts of Ontario.  相似文献   

G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)     

Philip J. Potts  Michael Thompson  Stephen Wilson 《Geostandards and Geoanalytical Research》2002,26(2):197-235

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.  相似文献   

Editorial     

Phil Potts  Mireille Polv 《Geostandards and Geoanalytical Research》2001,25(1):5-5

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